CobaltMaghrebV1, Main, Exploration, bibRecord, 000B25

Synthesis, crystal structure and magnetic properties of a new fluoride carbonate Ba2Co(CO3)2F2

Identifieur interne : 000B25 ( Main/Exploration ); précédent : 000B24; suivant : 000B26

Synthesis, crystal structure and magnetic properties of a new fluoride carbonate Ba2Co(CO3)2F2

Auteurs : A. Ben Ali [France] ; V. Maisonneuve [France] ; S. Kodjikian [France] ; L. S. Smiri [Tunisie] ; M. Leblanc [France]

Source :

Solid state sciences [ 1293-2558 ] ; 2002.

RBID : Pascal:02-0230687

Descripteurs français

Pascal (Inist)
- Etude expérimentale, Préparation chimique, Synthèse hydrothermale, Diffraction RX, Structure cristalline, Susceptibilité magnétique, Aimantation, Antiferromagnétisme, Baryum composé, Cobalt composé, 6166F, 7530C, Ba2Co(CO3)2F2, Ba C Co F O, Fluorocarbonate.

English descriptors

KwdEn :
- Antiferromagnetism, Barium compounds, Chemical preparation, Cobalt compounds, Crystal structure, Experimental study, Fluorocarbonates, Hydrothermal synthesis, Magnetic susceptibility, Magnetization, XRD.

Abstract

The structure of Ba₂Co(CO₃)₂F₂, obtained by hydrothermal synthesis, is determined from X-ray single crystal diffraction data (1085 unique reflections, R = 0.034, R_W = 0.078). Ba₂Co(CO₃)₂F₂ is orthorhombic, space group Pbca (Z = 4), with a = 6.6226(6), b = 11.494(2), c = 9.021(2) Å and V = 686.7(4) Å³. It can be described from infinite (010) layers of [CoO₄F₂] octahedra and CO^2-₃ entities or from [BaO₃F]∞ sheets of [BaO₇F₃] polyhedra. Antiferromagnetic order occurs below T_N 6 K.

Affiliations:

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Le document en format XML

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Co(CO<sub>3</sub>
)<sub>2</sub>
F<sub>2</sub>
</title>
<author><name sortKey="Ben Ali, A" sort="Ben Ali, A" uniqKey="Ben Ali A" first="A." last="Ben Ali">A. Ben Ali</name>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a">Synthesis, crystal structure and magnetic properties of a new fluoride carbonate Ba<sub>2</sub>
Co(CO<sub>3</sub>
)<sub>2</sub>
F<sub>2</sub>
</title>
<author><name sortKey="Ben Ali, A" sort="Ben Ali, A" uniqKey="Ben Ali A" first="A." last="Ben Ali">A. Ben Ali</name>
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<author><name sortKey="Maisonneuve, V" sort="Maisonneuve, V" uniqKey="Maisonneuve V" first="V." last="Maisonneuve">V. Maisonneuve</name>
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<placeName><region type="region" nuts="2">Pays de la Loire</region>
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</placeName>
<orgName type="university">Université du Maine</orgName>
</affiliation>
</author>
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<s2>72085 Le Mans</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
<sZ>3 aut.</sZ>
<sZ>5 aut.</sZ>
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<placeName><region type="region" nuts="2">Pays de la Loire</region>
<settlement type="city">Le Mans</settlement>
</placeName>
<orgName type="university">Université du Maine</orgName>
</affiliation>
</author>
<author><name sortKey="Smiri, L S" sort="Smiri, L S" uniqKey="Smiri L" first="L. S." last="Smiri">L. S. Smiri</name>
<affiliation wicri:level="1"><inist:fA14 i1="02"><s1>Laboratoire de Chimie Inorganique et Structurale, Faculté des Sciences de Bizerte</s1>
<s2>7021 Jarzouna</s2>
<s3>TUN</s3>
<sZ>4 aut.</sZ>
</inist:fA14>
<country>Tunisie</country>
<wicri:noRegion>7021 Jarzouna</wicri:noRegion>
</affiliation>
</author>
<author><name sortKey="Leblanc, M" sort="Leblanc, M" uniqKey="Leblanc M" first="M." last="Leblanc">M. Leblanc</name>
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<s2>72085 Le Mans</s2>
<s3>FRA</s3>
<sZ>1 aut.</sZ>
<sZ>2 aut.</sZ>
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<placeName><region type="region" nuts="2">Pays de la Loire</region>
<settlement type="city">Le Mans</settlement>
</placeName>
<orgName type="university">Université du Maine</orgName>
</affiliation>
</author>
</analytic>
<series><title level="j" type="main">Solid state sciences</title>
<title level="j" type="abbreviated">Solid state sci.</title>
<idno type="ISSN">1293-2558</idno>
<imprint><date when="2002">2002</date>
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<seriesStmt><title level="j" type="main">Solid state sciences</title>
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Antiferromagnetism</term>
<term>Barium compounds</term>
<term>Chemical preparation</term>
<term>Cobalt compounds</term>
<term>Crystal structure</term>
<term>Experimental study</term>
<term>Fluorocarbonates</term>
<term>Hydrothermal synthesis</term>
<term>Magnetic susceptibility</term>
<term>Magnetization</term>
<term>XRD</term>
</keywords>
<keywords scheme="Pascal" xml:lang="fr"><term>Etude expérimentale</term>
<term>Préparation chimique</term>
<term>Synthèse hydrothermale</term>
<term>Diffraction RX</term>
<term>Structure cristalline</term>
<term>Susceptibilité magnétique</term>
<term>Aimantation</term>
<term>Antiferromagnétisme</term>
<term>Baryum composé</term>
<term>Cobalt composé</term>
<term>6166F</term>
<term>7530C</term>
<term>Ba2Co(CO3)2F2</term>
<term>Ba C Co F O</term>
<term>Fluorocarbonate</term>
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<front><div type="abstract" xml:lang="en">The structure of Ba<sub>2</sub>
Co(CO<sub>3</sub>
)<sub>2</sub>
F<sub>2</sub>
, obtained by hydrothermal synthesis, is determined from X-ray single crystal diffraction data (1085 unique reflections, R = 0.034, R<sub>W</sub>
 = 0.078). Ba<sub>2</sub>
Co(CO<sub>3</sub>
)<sub>2</sub>
F<sub>2</sub>
 is orthorhombic, space group Pbca (Z = 4), with a = 6.6226(6), b = 11.494(2), c = 9.021(2) Å and V = 686.7(4) Å<sup>3</sup>
. It can be described from infinite (010) layers of [CoO<sub>4</sub>
F<sub>2</sub>
] octahedra and CO<sup>2-</sup>
<sub>3</sub>
 entities or from [BaO<sub>3</sub>
F]∞ sheets of [BaO<sub>7</sub>
F<sub>3</sub>
] polyhedra. Antiferromagnetic order occurs below T<sub>N</sub>
  6 K.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
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</country>
<region><li>Pays de la Loire</li>
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</orgName>
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<tree><country name="France"><region name="Pays de la Loire"><name sortKey="Ben Ali, A" sort="Ben Ali, A" uniqKey="Ben Ali A" first="A." last="Ben Ali">A. Ben Ali</name>
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<country name="Tunisie"><noRegion><name sortKey="Smiri, L S" sort="Smiri, L S" uniqKey="Smiri L" first="L. S." last="Smiri">L. S. Smiri</name>
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Synthesis, crystal structure and magnetic properties of a new fluoride carbonate Ba2Co(CO3)2F2

Synthesis, crystal structure and magnetic properties of a new fluoride carbonate Ba2Co(CO3)2F2

Source :

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

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Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri